Marvel Cinematic Universe: A Visual History
15. Captain America: The Winter Soldier (2014)
Captain America: The Winter Soldier totally shook up the MCU while also telling its own stand-alone story. S.H.I.E.L.D. was destroyed and Cap's old friend Bucky popped up as the brain-washed Winter Soldier.
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Introduces: Sam Wilson, Brock Rumlow, Batroc, Stephen Strange (mentioned), Wolfgang von Strucker (sting), Quicksilver (sting), Scarlet Witch (sting)
Post-Credits Scene: Once again there's two. The first shows an unaffected HYDRA base, where Loki's staff is being experimented on and a pair of "miracles" are held in captivity. The second sees Bucky begin to realise his past.
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