7. Baron Zemo (Daniel Brühl)
While Captain America: Civil War will see heroes vs heroes, there will be some more traditional villains in the movie as well. One of those is Frank Grillo's Crossbones, returning from The Winter Soldier, and the other big bad in the film will be Baron Helmut Zemo, played by Daniel Brühl. In the comics, Helmut is the son of the original Baron Zemo, Heinrich, who was a villain during World War II. This iteration is a major foe of Captain America, and in later years is the one responsible for revealing Bucky's past as The Winter Soldier to the world. The most notable part of the character, however, is perhaps the purple mask - worn by both father and son. However, Brühl
has said that his version won't have the iconic face-wear, and instead will be "loosely connected" to the character. It'll be interesting to see what this take on the character is like, and whether he'll be the main villain or if that role falls to Crossbones (there have been conflicting reports over this). Daniel Brühl, meanwhile, should be an excellent addition to the MCU, having impressed consistently since breaking through in Inglourious Basterds, most notably in Rush (about some guy called James Hunt) for which he received a number of awards nominations.