14. Crocodile Jump Escape (Live and Let Die, 1973)
http://youtu.be/ABBuCnaGW2U In Roger Moore's first outing as 007, Bond goes up against Dr. Kanaga (Yaphet Kotto), the dictator of a small Caribbean island, who, under the alias of Mr. Big, will distribute two tons of heroin to put rival drug dealers out of business. Once Kanaga tells Bond his plan, one of his henchman places Bond on a farm surrounded by crocodiles. In a daring feat of stunt work by Ross Kanaga, which took five takes, resulting in one where a crocodile tore Kanaga's trousers, Bond runs along the crocodiles' bodies to safety. It's one of those classic Bond moments that manages to be both tense and inventive.
13. Union Jack Parachute (The Spy Who Loved Me, 1977)
At the beginning of Moore's third Bond adventure, there's a ski chase involving Bond and Russian agents. Bond kills one using a gun device in his skis and escapes by jumping off a cliff. We see Bond falling and then a parachute in the design of the Union Jack opens, leading us in to the title sequence. Having Bond with a Union Jack design on his parachute is like a huge middle finger to the Russian agents chasing him. Along with the Bond theme accompanying it, it's also a perfect punctuation point to the pre-credits teaser. The stunt reportedly cost $500,000, the most expensive stunt at that time.