9. Messi vs Arsenal (2010)
http://youtu.be/3vaEzLp4CiI In what was one of the finest individual performances in living memory, Messi destroyed Arsenal almost single-handedly, scoring all four goals in their Champions League knockout round clash at Camp Nou. Although all of his goals on the night were good in their own right, it was his third that was the pick of the bunch. The then 22-year-old raced through on goal from the halfway line, before scooping a sensational effort over Gunners goalkeeper Manuel Almunia. It was a performance that left many speechless.