4. Tenacious D In The Pick of Destiny
Our second singing Satan of this list, and this time round he is the one threatening to dish out the buttsecks rather than being subjected to it. Coming at the end of an already hilariously awesome movie, this scene piques the catchy comedy musical styles of The D as they face off against the Devil, played quite extravagantly by a certain Mr. David Grohl. Do you remember in Tribute how Kage and Jables tell us they met a demon and played the greatest song in the world? Well, this is that encounter and it certainly doesn't disappoint. Watch the movie further and you'll also find out why it is they can't remember it, too.