10. Spider-Man
In Sam Raimi's 2002 version of Spider-Man we are given quite a romantic moment in the film, all caught in the rain. After becoming her hero and saving the day, Mary Jane (Kirsten Dunst) thanks an upside down Spidey (Tobey Maguire) the only way she can. By pulling his mask down just enough to plant a soft yet wet smooch on his lips. Although this scene adds a syrupy sweet taste to what became a franchise known for high flying action, it does work really well in the rain, adding just that touch of movie magic to make this scene a classic.