8. Spider-Man Punches Through Sandmans Body (Spider-Man 3)
When Spider-Man first encounters Flint Marko (the Sandman) in the final movie of the Raimi trilogy, it is when the latter is attempting to rob an armoured car while it is moving. Spidey swings through the streets and enters the car through the hole in the roof that Marko had entered through. The webbed wonder tells Sandman that he's been caught and should give up - to which Marko replies that he doesn't want to hurt Spidey and tells him to leave. Spidey, assuming that Marko is an ordinary human, laughs at that and says "I guess you haven't heard; I'm the sheriff around these parts" and Marko tests the theory by swinging a couple of punches, which Spidey dodges. The hero responds with a punch of his own but, to his surprise, his hand goes straight through Sandman's body (which is, of course, composed largely of sand). At that point, Marko's response is to turn his fist in to solidified sand and deliver a pummelling right hand to Spidey, which sends him flying out of the back of the vehicle.