5. Firefly
Who He Is: A villain who uses lighting and optical illusions to orchestrate his escape. His true name is Garfield Lynns, who was formerly a visual effects artist, who eventually switches to a life of crime. Originally introduced in 1952, the Firefly mantle was eventually passed on to Ted Carson in 1959.
Special Powers/Skills: He is best known for his battle suit which enables him to glide very well, and which is equipped with a flamethrower. Because let's face it, if you've designed a flying crime suit, the only way to make it cooler is with fire.
Who Should Portray Him: For no particular reason, I say Jon Hamm. It just feels right.