10 TV Couples That Should've Ended Up Together (But Didn't)

4. Nate And Serena - Gossip Girl

From the very first episode, Gossip Girl was all about making and breaking relationships. Even though Serena hooked up with her fair share of men, the hottest scenes involved her and Nate. Of course, their sex lives weren't the only good thing about the pair.

Like most of the characters on the show, they both grew up with rich parents, so they were used to the same type of lifestyle. They were always there for each other, and stayed friends even when Serena's friendship with her best friend was on the line.

Sure, they did some horrible things to each other, but so did Chuck and Blair, who were the star couple of the show.