7. Samantha Finn
Samantha Finn appeared in the sixth season of Buffy the Vampire Slayer in the episode "As You Were". She was a former member of the Peace Corps and the wife of Buffy's ex-boyfriend, Riley Finn, who was now a member of the army who dealt with the paranormal (along with Riley). The pair arrived in Sunnydale having "recruited" the Slayer to help them track and kill a rare Suvolte demon that they had followed across Central America as it killed everything in its path. Despite the fact that Riley used to date Buffy, the Scoobies seemed to readily accept Samantha, which suggested that she was a rather nice woman (as well as being very attractive). She managed to make connections with all of them. For example, she commended Willow Rosenberg on her ability to quit magic and, when they parted ways, they promised to keep in touch. She also helped Xander Harris and Anya Jenkins with their stressful wedding planning, giving them some easy but productive ideas. She also believed that Dawn Summers was mature enough to hear about demons (which pleased Dawn) and, finally, Buffy herself admitted that she liked Sam, after she told Buffy that she is "legendary," in both the eyes of the world and Riley.