4. Rip Riley
Best Quote: And then I'll shoot you, with a flare, and then I'll use a D ration bar and two survival crackers to make Smores over the crackling fire that used to be your chest cavity. If there was ever someone who could out-cool Archer he'd need a voice to match it. This was never any trouble for Patrick Warburton who is experienced in voice acting in animations most notably Joe from Family Guy and Brock Samson in the Venture Bros. His baritone builds upon his character's occupation as an adventurer and manhunter which of course raises him into the upper echelons of cool. He is clearly very capable, being an ex-ISIS field agent but this comes with some arrogance which occasionally leads to questionable decisions such as the seaplane he calls 'Loosey Goosey' which he is immensely defensive of despite its clear limitations. He and Archer are constantly at each others throats, mainly due to the latter's personality but also as it is implied that Rip once had a relationship with Malory which is a frequent hot button topic for Archer. His appearance was in the three part opening of the third season: Heart of Archness. With Archer seemingly kidnapped by pirates its up to Rip and the team to get him out. Although Rip loses his eye in the process the mission is a success and the episode proved Archer can be exciting as well as funny.